Issue 54, 2014
From the journal:

Chemical Communications

Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes†

Huanfeng Jiang,*a   Wanfei Yang,a   Huoji Chen,a   Jianxiao Lia  and  Wanqing Wua  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: jianghf@scut.edu.cn
Fax: +86 20-87112906
Tel: +86 20-87112906

Abstract

An aerobic oxidative cross-coupling reaction of alkenes with polyfluorobenzenes, through palladium-catalyzed allylic C–H activation, is reported. This attractive route provides a new way to forge allylic C–C bonds of valuable products, in good yields, with high regioselectivity.

Graphical abstract: Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes

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Article information

DOI
https://doi.org/10.1039/C4CC02023E
Article type
Communication
Submitted
18 Mar 2014
Accepted
15 Apr 2014
First published
16 Apr 2014

Chem. Commun., 2014,50, 7202-7204

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Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes

H. Jiang, W. Yang, H. Chen, J. Li and W. Wu, Chem. Commun., 2014, 50, 7202 DOI: 10.1039/C4CC02023E

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