Issue 45, 2014

A radical thia-Brook rearrangement

Abstract

Geminal mercapto trialkyl- and trialkoxy-silanes undergo an efficient radical chain rearrangement, whereby the silyl group migrates from carbon to sulfur; the starting materials are readily obtained by exploiting the peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkyl- or trialkoxy-vinylsilanes.

Graphical abstract: A radical thia-Brook rearrangement

Supplementary files

Article information

Article type
Communication
Submitted
05 Mar 2014
Accepted
14 Apr 2014
First published
17 Apr 2014

Chem. Commun., 2014,50, 5990-5992

A radical thia-Brook rearrangement

B. Quiclet-Sire and S. Z. Zard, Chem. Commun., 2014, 50, 5990 DOI: 10.1039/C4CC01683A

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