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Issue 43, 2014
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Room-temperature Cu(II)-catalyzed aromatic C–H azidation for the synthesis of ortho-azido anilines with excellent regioselectivity

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Abstract

Cu(II)-catalyzed aromatic C–H azidation with azido-benziodoxolone under mild conditions has been described. The primary amine exhibits an excellent ortho-directing effect, providing ortho-azidated anilines as the sole products.

Graphical abstract: Room-temperature Cu(ii)-catalyzed aromatic C–H azidation for the synthesis of ortho-azido anilines with excellent regioselectivity

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Publication details

The article was received on 26 Feb 2014, accepted on 12 Apr 2014 and first published on 14 Apr 2014


Article type: Communication
DOI: 10.1039/C4CC01481B
Citation: Chem. Commun., 2014,50, 5733-5736
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    Room-temperature Cu(II)-catalyzed aromatic C–H azidation for the synthesis of ortho-azido anilines with excellent regioselectivity

    Y. Fan, W. Wan, G. Ma, W. Gao, H. Jiang, S. Zhu and J. Hao, Chem. Commun., 2014, 50, 5733
    DOI: 10.1039/C4CC01481B

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