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Issue 56, 2014
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Synthesis, stability and reactivity of the first mononuclear nonheme oxoiron(IV) species with monoamido ligation: a putative reactive species generated from iron-bleomycin

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Abstract

The preparation and characterisation of an oxoiron(IV) species with monoamido ligation are described. Reactivity studies revealed the important role of the amido ligand in enhancing the ability of oxoiron(IV) complexes to promote hydrogen atom transfer from external alkanes.

Graphical abstract: Synthesis, stability and reactivity of the first mononuclear nonheme oxoiron(iv) species with monoamido ligation: a putative reactive species generated from iron-bleomycin

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Publication details

The article was received on 24 Feb 2014, accepted on 16 May 2014 and first published on 19 May 2014


Article type: Communication
DOI: 10.1039/C4CC01409J
Citation: Chem. Commun., 2014,50, 7485-7487
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    Synthesis, stability and reactivity of the first mononuclear nonheme oxoiron(IV) species with monoamido ligation: a putative reactive species generated from iron-bleomycin

    Y. Hitomi, K. Arakawa and M. Kodera, Chem. Commun., 2014, 50, 7485
    DOI: 10.1039/C4CC01409J

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