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Issue 36, 2014
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A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes

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Abstract

The first stable dianionic Janus-type bis(maloNHC) was isolated and characterized. Details on the chemistry of this biscarbene with respect to its ability to support catalytically relevant metal complexes are provided. The molecular structures of two dinuclear gold and silver complexes were determined by X-ray crystallography.

Graphical abstract: A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes

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Publication details

The article was received on 14 Feb 2014, accepted on 22 Mar 2014 and first published on 24 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC01200C
Citation: Chem. Commun., 2014,50, 4725-4728
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    A stable Janus bis(maloNHC) and its zwitterionic coinage metal complexes

    D. Tapu, Z. McCarty and C. McMillen, Chem. Commun., 2014, 50, 4725
    DOI: 10.1039/C4CC01200C

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