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Issue 33, 2014
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Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

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Abstract

A μ-oxo dimer of phosphorus(V) tetrabenzotriazacorrole (PTBC) has been synthesized and characterized for the first time. Spectroscopic and theoretical analysis support the opinion that two PTBC chromophore groups interact with each other, while the low-symmetric PTBC structure is also efficient for generating singlet oxygen.

Graphical abstract: Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

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Publication details

The article was received on 12 Feb 2014, accepted on 25 Feb 2014 and first published on 26 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC01115E
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 4312-4314
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    Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

    T. Furuyama, Y. Sugiya and N. Kobayashi, Chem. Commun., 2014, 50, 4312
    DOI: 10.1039/C4CC01115E

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