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Issue 28, 2014
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Expeditious synthesis of 1-aminoindane derivatives achieved by [1,4]-hydride shift mediated C(sp3)–H bond functionalization

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Abstract

Described herein is a [1,4]-hydride shift mediated expeditious synthesis of 1-aminoindane derivatives. A wide variety of substrates could be employed in this reaction to afford various indane derivatives in good to excellent chemical yields. Examination of the amine moiety revealed that the sterically hindered amine is the key to achieving both low catalyst loading and excellent chemical yields.

Graphical abstract: Expeditious synthesis of 1-aminoindane derivatives achieved by [1,4]-hydride shift mediated C(sp3)–H bond functionalization

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Publication details

The article was received on 03 Feb 2014, accepted on 13 Feb 2014 and first published on 14 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00894D
Citation: Chem. Commun., 2014,50, 3729-3731
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    Expeditious synthesis of 1-aminoindane derivatives achieved by [1,4]-hydride shift mediated C(sp3)–H bond functionalization

    K. Mori, K. Kurihara and T. Akiyama, Chem. Commun., 2014, 50, 3729
    DOI: 10.1039/C4CC00894D

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