Issue 31, 2014

Supramolecular association behavior of a strong C60 receptor with conjugated pentacene and tetrathiafulvalene moieties in solution and in the solid state

Abstract

A π-extended tetrathiafulvalene (exTTF) containing a conjugated pentacene moiety showed a large binding affinity toward C60 in solution. The crystal structure analysis of the cocrystal formed by this exTTF and C60 revealed that strong π–π interactions existed between C60 and naphthalene and 1,3-dithiol-2-ylidene units.

Graphical abstract: Supramolecular association behavior of a strong C60 receptor with conjugated pentacene and tetrathiafulvalene moieties in solution and in the solid state

Supplementary files

Article information

Article type
Communication
Submitted
28 Jan 2014
Accepted
25 Feb 2014
First published
25 Feb 2014

Chem. Commun., 2014,50, 4082-4084

Supramolecular association behavior of a strong C60 receptor with conjugated pentacene and tetrathiafulvalene moieties in solution and in the solid state

Z. Zhou, Y. Qin, W. Xu and D. Zhu, Chem. Commun., 2014, 50, 4082 DOI: 10.1039/C4CC00741G

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