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Issue 26, 2014
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κ2-Coordination of 18-crown-6 to Ce(III) cations: solution dynamics and reactivity

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Abstract

The coordination of 18-crown-6 to Ce[N(SiMe3)PhF]3 (PhF = pentafluorophenyl) results in a κ2-18-crown-6 complex, a unique coordination mode for an f-block cation. The κ2-18-crown-6 complex showed exchange with free 18-crown-6 in solution and facile rearrangement of the crown ligand into a κ6-18-crown-6 cerium complex.

Graphical abstract: κ2-Coordination of 18-crown-6 to Ce(iii) cations: solution dynamics and reactivity

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Publication details

The article was received on 18 Jan 2014, accepted on 09 Feb 2014 and first published on 10 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00448E
Citation: Chem. Commun., 2014,50, 3470-3472
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    κ2-Coordination of 18-crown-6 to Ce(III) cations: solution dynamics and reactivity

    H. Yin, J. R. Robinson, P. J. Carroll, P. J. Walsh and E. J. Schelter, Chem. Commun., 2014, 50, 3470
    DOI: 10.1039/C4CC00448E

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