Issue 18, 2014
From the journal:

Chemical Communications

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium†

Valeri Leich,a   Thomas P. Spaniol,a   Laurent Maronb  and  Jun Okuda*a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany
E-mail: jun.okuda@ac.rwth-aachen.de

b Université de Toulouse et CNRS INSA, UPS, CNRS, UMR 5215, LPCNO, 135 avenue de Rangueil, 31077 Toulouse, France
E-mail: Laurent.maron@irsamc.ups-tlse.fr

Abstract

Bis(triphenylsilyl)calcium [Ca(SiPh3)2(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C–C double bonds efficiently and regioselectively.

Graphical abstract: Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

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Article information

DOI
https://doi.org/10.1039/C3CC49308C
Article type
Communication
Submitted
07 Dec 2013
Accepted
07 Jan 2014
First published
07 Jan 2014

Chem. Commun., 2014,50, 2311-2314

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Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

V. Leich, T. P. Spaniol, L. Maron and J. Okuda, Chem. Commun., 2014, 50, 2311 DOI: 10.1039/C3CC49308C

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