Issue 16, 2014

Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

Abstract

The reaction of phosphine gas with a low coordinate diaryl germylene or diarylstannylene results in both oxidative addition and arene elimination at the group 14 atom. The products were characterised by 31P NMR spectroscopy and X-ray crystallography, and represent the first P–H bond activation by a heavy group 14 element compound.

Graphical abstract: Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

Supplementary files

Article information

Article type
Communication
Submitted
22 Nov 2013
Accepted
09 Dec 2013
First published
09 Dec 2013

Chem. Commun., 2014,50, 1944-1946

Author version available

Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

J. W. Dube, Z. D. Brown, C. A. Caputo, P. P. Power and P. J. Ragogna, Chem. Commun., 2014, 50, 1944 DOI: 10.1039/C3CC48933G

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