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Issue 16, 2014
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Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

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Abstract

The reaction of phosphine gas with a low coordinate diaryl germylene or diarylstannylene results in both oxidative addition and arene elimination at the group 14 atom. The products were characterised by 31P NMR spectroscopy and X-ray crystallography, and represent the first P–H bond activation by a heavy group 14 element compound.

Graphical abstract: Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

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Publication details

The article was received on 22 Nov 2013, accepted on 09 Dec 2013 and first published on 09 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48933G
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 1944-1946
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    Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

    J. W. Dube, Z. D. Brown, C. A. Caputo, P. P. Power and P. J. Ragogna, Chem. Commun., 2014, 50, 1944
    DOI: 10.1039/C3CC48933G

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