Issue 31, 2014
From the journal:

Chemical Communications

X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square†

Yoshihiro Sekine,a   Masayuki Nihei,a   Reiji Kumai,b   Hironori Nakao,b   Youichi Murakamib  and  Hiroki Oshio*a  

* Corresponding authors

a Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
E-mail: oshio@chem.tsukuba.ac.jp
Fax: +81-29-853-4238
Tel: +81-29-853-4238

b Photon Factory and Condensed Matter Research Center, Institute of Materials Structures Sciences, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan

Abstract

A cyanide-bridged tetranuclear Fe–Co complex showed electron-transfer-coupled spin transitions induced by X-ray irradiation. Single crystal X-ray diffraction measurements and X-ray absorption spectroscopy revealed that the X-ray-induced phase transition ratio was significantly altered by the selective excitation of the metal ions.

Graphical abstract: X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

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Article information

DOI
https://doi.org/10.1039/C3CC48820A
Article type
Communication
Submitted
19 Nov 2013
Accepted
17 Jan 2014
First published
20 Jan 2014

Chem. Commun., 2014,50, 4050-4052

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X-ray-induced phase transitions by selective excitation of heterometal ions in a cyanide-bridged Fe–Co molecular square

Y. Sekine, M. Nihei, R. Kumai, H. Nakao, Y. Murakami and H. Oshio, Chem. Commun., 2014, 50, 4050 DOI: 10.1039/C3CC48820A

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