Synthesis, structure and reactivity of FeII/III–NH3 complexes bearing a tripodal sulfonamido ligand

Nathaniel S. Sickerman; Sonja M. Peterson; Joseph W. Ziller; A. S. Borovik

doi:10.1039/C3CC48804G

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Synthesis, structure and reactivity of Fe^II/III–NH₃ complexes bearing a tripodal sulfonamido ligand†

Nathaniel S. Sickerman,^a Sonja M. Peterson,^a Joseph W. Ziller^a and A. S. Borovik*^a

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^a Department of Chemistry, University of California-Irvine, 1102 Natural Sciences II, Irvine, CA, USA
E-mail: aborovik@uci.edu

Abstract

Complexes [MⁿMST(NH₃)]ⁿ⁻³ (Mⁿ = Fe^II, Fe^III, Ga^III) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the Fe^III–NH₃ complex afforded a putative [Fe^IIIMST(NH₂)]⁻ species whose reactivity has been explored.

This article is part of the themed collection: Metal-Mediated Transformations of Small Molecules

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DOI: https://doi.org/10.1039/C3CC48804G
Article type: Communication
Submitted: 19 Nov 2013
Accepted: 09 Jan 2014
First published: 10 Jan 2014

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Chem. Commun., 2014,50, 2515-2517

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Synthesis, structure and reactivity of Fe^II/III–NH₃ complexes bearing a tripodal sulfonamido ligand

N. S. Sickerman, S. M. Peterson, J. W. Ziller and A. S. Borovik, Chem. Commun., 2014, 50, 2515 DOI: 10.1039/C3CC48804G

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