Issue 21, 2014

Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

Abstract

The bimetallic bis(pentalene) complex (μ:η55-Pn)2Ti2 reductively splits CO2 to form a bis(oxo) bridged dimer [(η8-Pn)Ti(μ-O)]2, in which the Ti–Ti bond has been cleaved, and the dicarbonyl complex (μ:η55-Pn)2[Ti(CO)]2.

Graphical abstract: Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

Supplementary files

Article information

Article type
Communication
Submitted
01 Nov 2013
Accepted
17 Jan 2014
First published
17 Jan 2014

Chem. Commun., 2014,50, 2769-2771

Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

A. F. R. Kilpatrick and F. G. N. Cloke, Chem. Commun., 2014, 50, 2769 DOI: 10.1039/C3CC48379G

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