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Issue 40, 2014
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Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones

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Abstract

A rhodium-catalyzed carbene transfer to alkynes is reported. Easily available enynones served as the carbene source replacing diazocompounds. The overall process involved a cyclization–cyclopropenation–ring enlargement sequence.

Graphical abstract: Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones

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Publication details

The article was received on 30 Sep 2013, accepted on 15 Oct 2013 and first published on 17 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47481J
Citation: Chem. Commun., 2014,50, 5379-5381
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    Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones

    M. J. González, E. López and R. Vicente, Chem. Commun., 2014, 50, 5379
    DOI: 10.1039/C3CC47481J

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