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Issue 40, 2014
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The final unadorned tris(azolyl)borate: finishing what Trofimenko started in 1966

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Abstract

The final addition to the tris(azolyl)borate ligand family, tris(1,2,3-triazolyl)borate, has been synthesized. The sodium salt of the ligand forms a complex polymeric structure where both N2 and N3 bind to crystallographically independent sodium ions. Depending on the divalent transition metal, tris(1,2,3-triazolyl)borate forms either molecular homoleptic complexes or coordination polymers.

Graphical abstract: The final unadorned tris(azolyl)borate: finishing what Trofimenko started in 1966

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Publication details

The article was received on 18 Sep 2013, accepted on 20 Oct 2013 and first published on 28 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47151A
Citation: Chem. Commun., 2014,50, 5273-5275
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    The final unadorned tris(azolyl)borate: finishing what Trofimenko started in 1966

    B. C. Hughes, Z. Lu and D. M. Jenkins, Chem. Commun., 2014, 50, 5273
    DOI: 10.1039/C3CC47151A

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