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Issue 7, 2014
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Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets

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Abstract

The first application of 1-methyl-1H-pyrrole-2-carbaldehyde oxime as a ligand for the coordination of paramagnetic transition metal ions has afforded a new {MnIII25} barrel-like cluster linked via Na+ cations into a 1D polymeric topology that exhibits single-molecule magnetic behaviour.

Graphical abstract: Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets

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Publication details

The article was received on 16 Sep 2013, accepted on 30 Oct 2013 and first published on 31 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC47094F
Citation: Chem. Commun., 2014,50, 779-781
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    Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets

    D. P. Giannopoulos, A. Thuijs, W. Wernsdorfer, M. Pilkington, G. Christou and T. C. Stamatatos, Chem. Commun., 2014, 50, 779
    DOI: 10.1039/C3CC47094F

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