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Issue 5, 2016
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Resolution of P-stereogenic P-heterocycles via the formation of diastereomeric molecular and coordination complexes (a review)

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Abstract

TADDOL derivatives and the Ca2+-salts of tartaric acid derivatives were found to be versatile and generally applicable resolving agents for the preparation of the enantiomers of P-stereogenic heterocyclic phosphine oxides and phosphinates via the formation of the corresponding diastereomeric molecular and coordination complexes. A few of the diastereomeric intermediates were characterized by single crystal X-ray crystallography to gain insights into the binding mode of the corresponding heterocyclic phosphine oxide (“guest”) and the resolving agent (“host”) and to study the underlying phenomenon of enantiomeric recognition.

Graphical abstract: Resolution of P-stereogenic P-heterocycles via the formation of diastereomeric molecular and coordination complexes (a review)

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Publication details

The article was received on 04 Aug 2015, accepted on 29 Oct 2015 and first published on 29 Oct 2015


Article type: Perspective
DOI: 10.1039/C5DT02999F
Citation: Dalton Trans., 2016,45, 1823-1842
  • Open access: Creative Commons BY-NC license
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    Resolution of P-stereogenic P-heterocycles via the formation of diastereomeric molecular and coordination complexes (a review)

    P. Bagi, V. Ujj, M. Czugler, E. Fogassy and G. Keglevich, Dalton Trans., 2016, 45, 1823
    DOI: 10.1039/C5DT02999F

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