Issue 87, 2018
From the journal:

Chemical Communications

Sensing the chirality of various organic solvents by helically arranged π-blades†

Yuki Shimizu,a   Yoshiaki Shoji, ORCID logo *a   Daisuke Hashizume,b   Yuuya Nagata ORCID logo c  and  Takanori Fukushima ORCID logo *a  

* Corresponding authors

a Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
E-mail: yshoji@res.titech.ac.jp, fukushima@res.titech.ac.jp

b RIKEN Center for Emergent Matter Science (CEMS), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

c Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

Although the chiral enrichment of dynamic prochiral molecules usually requires a strong interaction with a chiral source, the enantiomer ratio of a propeller-shaped molecule, obtained by a recently developed boron-mediated benzannulation reaction of alkynes, is biased in various organic solvents through solvation for the propeller moieties.

Graphical abstract: Sensing the chirality of various organic solvents by helically arranged π-blades

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Article information

DOI
https://doi.org/10.1039/C8CC06277C
Article type
Communication
Submitted
01 Aug 2018
Accepted
10 Sep 2018
First published
10 Sep 2018

Chem. Commun., 2018,54, 12314-12317

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Sensing the chirality of various organic solvents by helically arranged π-blades

Y. Shimizu, Y. Shoji, D. Hashizume, Y. Nagata and T. Fukushima, Chem. Commun., 2018, 54, 12314 DOI: 10.1039/C8CC06277C

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