Multifunctional all-TiO2 Bragg stacks based on blocking layer-assisted spin coating

Abstract

Multifunctional all-TiO₂ Bragg stacks displaying structural color are fabricated by sequentially spin coating two TiO₂ nanoparticles of different shapes and sizes. We find that Bragg stacks generated by simple sequential deposition of the two nanoparticles have poor reflective properties compared to what would be expected based on the optical properties of individual TiO₂ nanoparticle layers. This poor photonic property is due to the cross-contamination of neighboring layers during the deposition process; that is, small TiO₂ nanoparticles infiltrate the pre-existing TiO₂ nanoparticle layers, changing their optical properties. A sacrificial polymer-blocking layer is added between the low- and high-refractive-index layers to prevent their cross-contamination upon fabrication, which, in turn, significantly improves the overall photonic performance of these all-TiO₂ Bragg stacks. All-TiO₂ Bragg stacks exhibit excellent superhydrophilicity and self-cleaning properties, due to the porosity of the stacked structure and the photocatalytic nature of TiO₂ nanoparticles, respectively, enabling patterning of wettability in these multilayer structures. Additionally, we demonstrate that the high quality photonic properties of these all-TiO₂ multilayer structures render them ideal for use in enhancing the energy conversion efficiency of dye-sensitized solar cells (DSSCs).