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Issue 39, 2013
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Bismuth oxide: a new lithium-ion battery anode

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Abstract

Bismuth oxide directly grown on nickel foam (p-Bi2O3/Ni) was prepared by a facile polymer-assisted solution approach and was used directly as a lithium-ion battery anode for the first time. The Bi2O3 particles were covered with thin carbon layers, forming network-like sheets on the surface of the Ni foam. The binder-free p-Bi2O3/Ni shows superior electrochemical properties with a capacity of 668 mA h g−1 at a current density of 800 mA g−1, which is much higher than that of commercial Bi2O3 powder (c-Bi2O3) and Bi2O3 powder prepared by the polymer-assisted solution method (p-Bi2O3). The good performance of p-Bi2O3/Ni can be attributed to higher volumetric utilization efficiency, better connection of active materials to the current collector, and shorter lithium ion diffusion path.

Graphical abstract: Bismuth oxide: a new lithium-ion battery anode

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Publication details

The article was received on 09 Jul 2013, accepted on 06 Aug 2013 and first published on 07 Aug 2013


Article type: Paper
DOI: 10.1039/C3TA12655B
Citation: J. Mater. Chem. A, 2013,1, 12123-12127
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    Bismuth oxide: a new lithium-ion battery anode

    Y. Li, M. A. Trujillo, E. Fu, B. Patterson, L. Fei, Y. Xu, S. Deng, S. Smirnov and H. Luo, J. Mater. Chem. A, 2013, 1, 12123
    DOI: 10.1039/C3TA12655B

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