Issue 11, 2013
From the journal:

Journal of Materials Chemistry A

Fe2+-based layered porous coordination polymers and soft encapsulation of guests via redox activity†

Satoshi Horike,*ab   Masayuki Sugimoto,a   Kanokwan Kongpatpanich,a   Yuh Hijikata,a   Munehiro Inukai,c   Daiki Umeyama,a   Shinji Kitao,d   Makoto Setod  and  Susumu Kitagawa*ace  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: kitagawa@icems.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2736

b Japan Science and Technology Agency, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

c Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

d Research Reactor Institute, Kyoto University, Kumatori, Osaka 590-0494, Japan

e ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park, Shimogyo-ku, Kyoto 600-8815, Japan

Abstract

2-D layer type porous coordination polymers containing redox active Fe2+ centers were synthesized. One of the compounds [Fe(isophthalate)(4,4′-bipyridyl)] showed structural flexibility via guest adsorption, and we observed reversible Fe2+ and Fe3+ switching by iodine insertion. The composite showed electric conductivity.

Graphical abstract: Fe2+-based layered porous coordination polymers and soft encapsulation of guests via redox activity

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Article information

DOI
https://doi.org/10.1039/C3TA01414B
Article type
Paper
Submitted
07 Dec 2012
Accepted
18 Jan 2013
First published
21 Jan 2013

J. Mater. Chem. A, 2013,1, 3675-3679

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Fe2+-based layered porous coordination polymers and soft encapsulation of guests via redox activity

S. Horike, M. Sugimoto, K. Kongpatpanich, Y. Hijikata, M. Inukai, D. Umeyama, S. Kitao, M. Seto and S. Kitagawa, J. Mater. Chem. A, 2013, 1, 3675 DOI: 10.1039/C3TA01414B

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