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Issue 3, 2013
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Microporous metal–organic frameworks with open metal sites as sorbents for selective gas adsorption and fluorescence sensors for metal ions

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Abstract

Two cluster-based microporous MOFs containing coordination unsaturated metal(II) sites (or open metal(II) sites) have been constructed from boxlike or cagelike {M3}x SBUs. They both exhibit highly selective uptake for CO2 over CH4 and N2 under ambient conditions. More importantly, MOF-1 also provides an ideal luminescence sensor for selective probing Ba2+ and Cu2+ ions based on significant luminescence enhancement or quenching.

Graphical abstract: Microporous metal–organic frameworks with open metal sites as sorbents for selective gas adsorption and fluorescence sensors for metal ions

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Publication details

The article was received on 10 Oct 2012, accepted on 15 Nov 2012 and first published on 15 Nov 2012


Article type: Communication
DOI: 10.1039/C2TA00635A
Citation: J. Mater. Chem. A, 2013,1, 495-499
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    Microporous metal–organic frameworks with open metal sites as sorbents for selective gas adsorption and fluorescence sensors for metal ions

    Y. Li, J. Li, L. Wang, B. Zhou, Q. Chen and X. Bu, J. Mater. Chem. A, 2013, 1, 495
    DOI: 10.1039/C2TA00635A

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