Issue 1, 2014

Photoredox activation and anion binding catalysis in the dual catalytic enantioselective synthesis of β-amino esters

Abstract

The enantioselective oxidative C–H functionalization of tetrahydroisoquinoline derivatives is achieved through the merger of photoredox and asymmetric anion-binding catalysis. This combination of two distinct catalysis concepts introduces a potentially general approach to asymmetric transformations in oxidative photocatalysis.

Graphical abstract: Photoredox activation and anion binding catalysis in the dual catalytic enantioselective synthesis of β-amino esters

Supplementary files

Article information

Article type
Edge Article
Submitted
12 Aug 2013
Accepted
22 Aug 2013
First published
23 Aug 2013

Chem. Sci., 2014,5, 112-116

Photoredox activation and anion binding catalysis in the dual catalytic enantioselective synthesis of β-amino esters

G. Bergonzini, C. S. Schindler, C. Wallentin, E. N. Jacobsen and C. R. J. Stephenson, Chem. Sci., 2014, 5, 112 DOI: 10.1039/C3SC52265B

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