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Issue 10, 2013
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Radical carbooxygenations of alkenes using hydroxamic acids

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Abstract

A radical-mediated approach to alkene carbooxygenation using hydroxamic acids is described. These transformations represent rare examples of direct carbooxygenations, and deliver versatile functionality to the unsaturated substrate. Included in this study are alkene oxyallylation, oxycyanation, and formal oxyacylation processes. These unique reactions capitalize on the reactivity of amidoxyl radicals in alkene additions.

Graphical abstract: Radical carbooxygenations of alkenes using hydroxamic acids

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Publication details

The article was received on 24 May 2013, accepted on 17 Jul 2013 and first published on 19 Jul 2013


Article type: Edge Article
DOI: 10.1039/C3SC51466H
Citation: Chem. Sci., 2013,4, 4030-4034
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    Radical carbooxygenations of alkenes using hydroxamic acids

    R. K. Quinn, V. A. Schmidt and E. J. Alexanian, Chem. Sci., 2013, 4, 4030
    DOI: 10.1039/C3SC51466H

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