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Issue 4, 2013
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Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal–organic polyhedral framework

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Abstract

The highly porous (3,24)-connected framework NOTT-122 incorporates a C3-symmetric angularly connected isophthalate linker containing 1,2,3-triazole rings and shows body-centered tetragonal packing of [Cu24(isophthalate)24] cuboctahedra. This unique packing, coupled with the high density of free N-donor sites, is responsible for the simultaneous high H2, CH4 and CO2 adsorption capacities in desolvated NOTT-122a.

Graphical abstract: Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal–organic polyhedral framework

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Publication details

The article was received on 16 Oct 2012, accepted on 31 Jan 2013 and first published on 11 Feb 2013


Article type: Edge Article
DOI: 10.1039/C3SC21769H
Citation: Chem. Sci., 2013,4, 1731-1736
  • Open access: Creative Commons BY license
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    Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal–organic polyhedral framework

    Y. Yan, M. Suyetin, E. Bichoutskaia, A. J. Blake, D. R. Allan, S. A. Barnett and M. Schröder, Chem. Sci., 2013, 4, 1731
    DOI: 10.1039/C3SC21769H

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