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Issue 4, 2013
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Thermal switching between blue and red luminescence in magnetic chiral cyanido-bridged EuIII–WV coordination helices

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Abstract

Unique one-dimensional cyanido-bridged {[EuIII(RR-Pri-Pybox)(dmf)4]3[WV(CN)8]3}n·dmf·8H2O (1-RR) and {[EuIII(SS-Pri-Pybox)(dmf)4]3[WV(CN)8]3}n·dmf·8H2O (1-SS) (Pri-Pybox = 2,2′-(2,6-pyridinediyl)bis(4-isopropyl-2-oxazoline)) chains were synthesized and characterized. They combine chiral helicity with paramagnetism and thermally switchable luminescence, and have a great potential in the aspect of magneto-optical phenomena.

Graphical abstract: Thermal switching between blue and red luminescence in magnetic chiral cyanido-bridged EuIII–WV coordination helices

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Publication details

The article was received on 23 Nov 2012, accepted on 23 Nov 2012 and first published on 26 Nov 2012


Article type: Communication
DOI: 10.1039/C2RA23033J
Citation: RSC Adv., 2013,3, 1065-1068
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    Thermal switching between blue and red luminescence in magnetic chiral cyanido-bridged EuIII–WV coordination helices

    S. Chorazy, K. Nakabayashi, N. Ozaki, R. Pełka, T. Fic, J. Mlynarski, B. Sieklucka and S. Ohkoshi, RSC Adv., 2013, 3, 1065
    DOI: 10.1039/C2RA23033J

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