Issue 16, 2013
From the journal:

Polymer Chemistry

Pillar[5]arene-based supramolecular polypseudorotaxane polymer networks constructed by orthogonal self-assembly†

Xiao-Yu Hu,a   Xuan Wu,a   Sai Wang,a   Dongzhong Chen,a   Wei Xia,a   Chen Lin,a   Yi Pana  and  Leyong Wang*a  

* Corresponding authors

a Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Chemistry, Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
E-mail: lywang@nju.edu.cn
Fax: +86 025-83317761
Tel: +86 025 83592529

Abstract

A novel pillar[5]arene-based supramolecular polypseudorotaxane network constructed by orthogonal self-assembly has been successfully fabricated. The obtained supramolecular polypseudorotaxane polymer was formed by a combination of two different non-covalent interactions, quadruple hydrogen bonding and pillararene-based host–guest interactions. Furthermore, a translucent film could be generated from the combination of this supramolecular polymer with PEG-2000 as the polymer matrix. The present study will provide a convenient and efficient way for the creation of pillararene-based advanced supramolecular materials.

Graphical abstract: Pillar[5]arene-based supramolecular polypseudorotaxane polymer networks constructed by orthogonal self-assembly

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Article information

DOI
https://doi.org/10.1039/C3PY00575E
Article type
Communication
Submitted
06 May 2013
Accepted
31 May 2013
First published
03 Jun 2013

Polym. Chem., 2013,4, 4292-4297

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Pillar[5]arene-based supramolecular polypseudorotaxane polymer networks constructed by orthogonal self-assembly

X. Hu, X. Wu, S. Wang, D. Chen, W. Xia, C. Lin, Y. Pan and L. Wang, Polym. Chem., 2013, 4, 4292 DOI: 10.1039/C3PY00575E

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