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Issue 2, 2013
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Synthesis and crystallinity of all-conjugated poly(3-hexylthiophene) block copolymers

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Abstract

A simplified approach towards the synthesis of high molecular weight (Mw > 50 kg mol−1) poly(3-hexylthiophene) (P3HT)-based all-conjugated block copolymers is demonstrated and applied to prepare a series of all-conjugated block copolymers. Grazing-incidence X-ray scattering measurements show that P3HT crystallization is suppressed in all-conjugated block copolymers with low (<25 wt%) P3HT content.

Graphical abstract: Synthesis and crystallinity of all-conjugated poly(3-hexylthiophene) block copolymers

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Publication details

The article was received on 07 Oct 2012, accepted on 19 Oct 2012 and first published on 22 Oct 2012


Article type: Communication
DOI: 10.1039/C2PY20830J
Citation: Polym. Chem., 2013,4, 229-232
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    Synthesis and crystallinity of all-conjugated poly(3-hexylthiophene) block copolymers

    Y. Lin, K. A. Smith, C. N. Kempf and R. Verduzco, Polym. Chem., 2013, 4, 229
    DOI: 10.1039/C2PY20830J

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