Issue 40, 2013
From the journal:

Organic & Biomolecular Chemistry

Rhodium(iii)-catalyzed ortho-olefination of aryl phosphonates†

Bathoju Chandra Charya  and  Sunggak Kim*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
E-mail: sgkim @ntu.edu.sg
Fax: +65 6791 1961
Tel: +65 6592 7765

Abstract

Rhodium(III)-catalyzed C–H olefination of aryl phosphonic esters is reported for the first time. In this mild and efficient process, the phosphonic ester group is utilized successfully as a new directing group. In addition, mono-olefination for aryl phosphonates is observed using a phosphonic diamide directing group.

Graphical abstract: Rhodium(iii)-catalyzed ortho-olefination of aryl phosphonates

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Article information

DOI
https://doi.org/10.1039/C3OB41548A
Article type
Communication
Submitted
29 Jul 2013
Accepted
19 Aug 2013
First published
20 Aug 2013

Org. Biomol. Chem., 2013,11, 6879-6882

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Rhodium(III)-catalyzed ortho-olefination of aryl phosphonates

B. C. Chary and S. Kim, Org. Biomol. Chem., 2013, 11, 6879 DOI: 10.1039/C3OB41548A

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