Issue 2, 2013

Pillar[5]arenes with an introverted amino group: a hydrogen bonding tuning effect

Abstract

Pillar[5]arenes with introverted amino groups were produced through aminolysis. X-ray analysis demonstrated that the intramolecular hydrogen bonding induced the amino group toward the inner space of the cavity. The kinetic studies and molecular modelings revealed that the hydrogen bonding also contributed to the acceleration of the aminolysis through stabilizing the intermediate.

Graphical abstract: Pillar[5]arenes with an introverted amino group: a hydrogen bonding tuning effect

Supplementary files

Article information

Article type
Communication
Submitted
19 Oct 2012
Accepted
07 Nov 2012
First published
07 Nov 2012

Org. Biomol. Chem., 2013,11, 248-251

Pillar[5]arenes with an introverted amino group: a hydrogen bonding tuning effect

L. Chen, Z. Li, Z. Chen and J. Hou, Org. Biomol. Chem., 2013, 11, 248 DOI: 10.1039/C2OB27044G

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