Issue 7, 2013
From the journal:

Organic & Biomolecular Chemistry

Synthesis of α-iodoketals from methyl ketonesvia sustainable and orthogonal tandem catalysis†

Yan Yang,a   Meng Gao,a   Wen-Ming Shu,a   Liu-Ming Wu,a   Dong-Xue Zhanga  and  An-Xin Wu*a  

* Corresponding authors

a Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, P. R. China
E-mail: chwuax@mail.ccnu.edu.cn
Tel: +86 027 6786 7773

Abstract

A highly efficient method for the direct synthesis of α-iodoketals from methyl ketones has been developed via sustainable integration of orthogonal tandem catalytic reactions: copper(II) oxide catalyzed iodination reaction and the subsequent excess or regenerated iodine catalyzed regioselective ketalization reaction.

Graphical abstract: Synthesis of α-iodoketals from methyl ketones via sustainable and orthogonal tandem catalysis

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Article information

DOI
https://doi.org/10.1039/C2OB27028E
Article type
Paper
Submitted
17 Oct 2012
Accepted
17 Dec 2012
First published
19 Dec 2012

Org. Biomol. Chem., 2013,11, 1226-1233

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Synthesis of α-iodoketals from methyl ketones via sustainable and orthogonal tandem catalysis

Y. Yang, M. Gao, W. Shu, L. Wu, D. Zhang and A. Wu, Org. Biomol. Chem., 2013, 11, 1226 DOI: 10.1039/C2OB27028E

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