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Issue 3, 2017
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Dicyanopyrazine capped with tetraphenylethylene: polymorphs with high contrast luminescence as organic volatile sensors

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Abstract

Recently the polymorphism and phase-transition between polymorphs have attracted special attention in organic luminescent materials. In this report, we employed propeller-like tetraphenylethylenes to functionalize large conjugated and electron-withdrawing dicyanopyrazine units, constructing novel organic luminescent polymorphs with high contrast fluorescence. Through an in-depth study of the luminescence-related properties, the more planar structured 2DQCN was found to generate close intermolecular packing and demonstrated essentially different solid state luminescence behaviour compared with that of 1DQCN. It shows crystallization-induced red-shift fluorescence, in contrast to the crystallization-induced blue-shift of 1DQCN and many other AIE (aggregation-induced emission) materials. The morphology transformation of 2DQCN can be realized via solvent fuming and thermal annealing, where the transformation among its three forms was manifested by DSC measurements. Utilizing the high contrast luminescence of 2DQCN polymorphs, we demonstrated their real applications as selective visual sensors for detecting volatile organic compounds. The results, revealing insights into the structure–property relationship of luminescent polymorphs, should provide useful directions for the understanding, design and utilization of luminescent colour-switching materials.

Graphical abstract: Dicyanopyrazine capped with tetraphenylethylene: polymorphs with high contrast luminescence as organic volatile sensors

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Publication details

The article was received on 28 Jul 2016, accepted on 04 Sep 2016 and first published on 12 Sep 2016


Article type: Research Article
DOI: 10.1039/C6QM00146G
Citation: Mater. Chem. Front., 2017,1, 530-537
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    Dicyanopyrazine capped with tetraphenylethylene: polymorphs with high contrast luminescence as organic volatile sensors

    C. Ge, Y. Liu, X. Ye, X. Zheng, Q. Han, J. Liu and X. Tao, Mater. Chem. Front., 2017, 1, 530
    DOI: 10.1039/C6QM00146G

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