Issue 8, 2013
From the journal:

New Journal of Chemistry

Bromine kinetic isotope effects: insight into Grignard reagent formation†

Lukasz Szatkowski,a   Agnieszka Dybala-Defratyka,*a   Charlie Batarseh,b   Jochanan Blum,b   Ludwik Haliczc  and  Faina Gelman*c  

* Corresponding authors

a Institute of Applied Radiation Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
E-mail: agnieszka.dybala-defratyka@p.lodz.pl
Tel: +48 42 631 3198

b Department of Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel

c Geological Survey of Israel, Malkhei Israel 30, Jerusalem 95501, Israel
E-mail: faina@gsi.gov.il
Tel: +972 25 314 208

Abstract

The study focuses on the determination of bromine kinetic isotope effects (Br-KIEs) on Grignard reagent formation applying compound specific bromine isotope analysis. Clear difference between the Br-KIE values for aromatic and aliphatic bromides was observed. The measured Br-KIE values were found to be in a good agreement with the theoretical predictions.

Graphical abstract: Bromine kinetic isotope effects: insight into Grignard reagent formation

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3NJ00197K
Article type
Letter
Submitted
20 Feb 2013
Accepted
25 Mar 2013
First published
26 Mar 2013

New J. Chem., 2013,37, 2241-2244

Permissions

Request permissions

Bromine kinetic isotope effects: insight into Grignard reagent formation

L. Szatkowski, A. Dybala-Defratyka, C. Batarseh, J. Blum, L. Halicz and F. Gelman, New J. Chem., 2013, 37, 2241 DOI: 10.1039/C3NJ00197K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements