Issue 11, 2013
From the journal:

Green Chemistry

Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile†

Cyrille Guillon,ab   Carsten Liebig,abc   Sébastien Paul,bd   Anne-Sophie Mamede,ab   Wolfgang F. Hölderich,c   Franck Dumeignilabe  and  Benjamin Katryniok*bd  

* Corresponding authors

a Univ. Lille Nord de France, Lille, France

b Unité de Catalyse et de Chimie du Solide, UCCS (UMR CNRS 8181), Cité Scientifique, Villeneuve d‘Ascq, France
E-mail: benjamin.katryniok@ec-lille.fr

c Department of Chemical Technology and Heterogeneous Catalysis, RWTH Aachen University, Worringerweg 1, D-52074 Aachen, Germany

d Ecole Centrale de Lille, ECLille, F-59655 Villeneuve d'Ascq, France

e Institut Universitaire de France, Maison des Universités, 103 Boulevard Saint-Michel, 75005 Paris, France

Abstract

The ammoxidation of allyl alcohol was demonstrated over antimony–iron oxide catalysts with a Sb/Fe ratio of 0.6 and 1. Both catalysts showed high performance with 83 and 84% yield of acrylonitrile, respectively, whereby the main difference was found in the initial performance. This was ascribed to the in-operando formation of the SbFeO4 mixed oxide on the catalyst surface under reaction conditions, as proven by XPS analysis.

Graphical abstract: Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile

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Article information

DOI
https://doi.org/10.1039/C3GC41089G
Article type
Communication
Submitted
07 Jun 2013
Accepted
12 Aug 2013
First published
12 Aug 2013

Green Chem., 2013,15, 3015-3019

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Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile

C. Guillon, C. Liebig, S. Paul, A. Mamede, W. F. Hölderich, F. Dumeignil and B. Katryniok, Green Chem., 2013, 15, 3015 DOI: 10.1039/C3GC41089G

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