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Issue 1, 2014
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Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(IV), a non-O-donating oxidant

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Abstract

A biomimetic di-Mn catalyst catalyzes water oxidation with (NH4)2Ce(NO3)6 for >7 days with initial TOF of 40 h−1. Isolation of one molecule of catalyst in each pore of a Cr-based MOF prevents decomposition of the catalyst and allows sustained water oxidation even at pH 1.00.

Graphical abstract: Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(iv), a non-O-donating oxidant

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Publication details

The article was received on 10 Sep 2013, accepted on 30 Oct 2013 and first published on 04 Nov 2013


Article type: Communication
DOI: 10.1039/C3EE43040E
Citation: Energy Environ. Sci., 2014,7, 317-322
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    Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(IV), a non-O-donating oxidant

    R. E. Hansen and S. Das, Energy Environ. Sci., 2014, 7, 317
    DOI: 10.1039/C3EE43040E

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