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Issue 2, 2013
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Interfaces between water splitting catalysts and buried silicon junctions

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Abstract

The coupling of water-splitting catalysts to silicon photovoltaics enables direct solar-to-fuel conversion. Critical to the performance of such devices is the use of interfaces to protect silicon from the oxygen-evolving reaction (OER) and at the same time to provide Ohmic contact between the buried silicon junction and the immobilised OER catalyst. Presented herein are guidelines for constructing the Si|catalyst interface, which is a crucial building block for efficient direct solar-to-fuel conversion devices. We show that fluorinated-tin-oxide is an especially attractive interface for buried-junction devices.

Graphical abstract: Interfaces between water splitting catalysts and buried silicon junctions

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Publication details

The article was received on 30 Oct 2012, accepted on 05 Dec 2012, published on 06 Dec 2012 and first published online on 06 Dec 2012


Article type: Paper
DOI: 10.1039/C2EE23932A
Citation: Energy Environ. Sci., 2013,6, 532-538
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    Interfaces between water splitting catalysts and buried silicon junctions

    C. R. Cox, M. T. Winkler, J. J. H. Pijpers, T. Buonassisi and D. G. Nocera, Energy Environ. Sci., 2013, 6, 532
    DOI: 10.1039/C2EE23932A

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