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Issue 44, 2013
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Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: direct formation of enantiopure systems for circularly polarised luminescence applications

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Abstract

Mono-C-substitution of the 1,4,7-triazacyclononane ring induces formation of single enantiomers of Eu(III) complexes with nonadentate N6O3 ligands. The absolute configuration of each complex is determined by the stereogenicity of the C-substituent, revealed by comparison of the sign and sequence of CPL transitions for a series of complexes.

Graphical abstract: Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: direct formation of enantiopure systems for circularly polarised luminescence applications

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Publication details

The article was received on 08 Jul 2013, accepted on 09 Sep 2013 and first published on 13 Sep 2013


Article type: Paper
DOI: 10.1039/C3DT52425F
Citation: Dalton Trans., 2013,42, 15610-15616
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    Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: direct formation of enantiopure systems for circularly polarised luminescence applications

    N. H. Evans, R. Carr, M. Delbianco, R. Pal, D. S. Yufit and D. Parker, Dalton Trans., 2013, 42, 15610
    DOI: 10.1039/C3DT52425F

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