Inorganic click (iClick) synthesis of heterotrinuclear PtII/AuI2 complexes

Andrew R. Powers; Xi Yang; Trevor J. Del Castillo; Ion Ghiviriga; Khalil A. Abboud; Adam S. Veige

doi:10.1039/C3DT52105B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Inorganic click (iClick) synthesis of heterotrinuclear Pt^II/Au^I₂ complexes†

Andrew R. Powers,^a Xi Yang,^a Trevor J. Del Castillo,^a Ion Ghiviriga,^a Khalil A. Abboud^a and Adam S. Veige*^a

Author affiliations

* Corresponding authors

^a University of Florida, Center for Catalysis, Department of Chemistry, P.O. Box 117200, Gainesville, Florida 32611, USA
E-mail: veige@chem.ufl.edu
Fax: +1 352-392-3255
Tel: +1 352-392-9844

Abstract

Metal-azide–metal-acetylide cycloaddition (iClick) reactions to synthesize heterotrimetallics and an unexpected novel tetranuclear gold(I) complex, are described. In addition, a discussion regarding the connection between traditional azide–alkyne cycloaddition reactions and iClick is presented focusing on applications towards linking multiple metal ions.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3DT52105B
Article type: Communication
Submitted: 02 Aug 2013
Accepted: 04 Sep 2013
First published: 04 Sep 2013

Download Citation

Dalton Trans., 2013,42, 14963-14966

Permissions

Request permissions

Inorganic click (iClick) synthesis of heterotrinuclear Pt^II/Au^I₂ complexes

A. R. Powers, X. Yang, T. J. Del Castillo, I. Ghiviriga, K. A. Abboud and A. S. Veige, Dalton Trans., 2013, 42, 14963 DOI: 10.1039/C3DT52105B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions