Issue 18, 2013
From the journal:

Dalton Transactions

LiCu2[BP2O8(OH)2]: a chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization†

Miao Yang,*ab   Xinjie Li,ad   Jihong Yu,*c   Jingran Zhu,c   Xiaoxia Liu,d   Genfu Chene  and  Yan Yanc  

* Corresponding authors

a China Ionic Liquid Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road 457, Dalian, P. R. China
E-mail: yangmiao@dicp.ac.cn

b National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China

c State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: jihong@jlu.edu.cn

d Department of Chemistry, Northeastern University, Shenyang 110004, P. R. China

e National Laboratory for Superconductivity, Institute of Physics and Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China

Abstract

A new chiral copper borophosphate, LiCu2[BP2O8(OH)2] (1), was crystallized from achiral inorganic raw materials in boric acid flux reaction. The structure features a 9-ring channel enclosed by triple right-handed helices. The bulk sample exhibits optical activity confirmed by circular dichroism (CD) spectra, indicating an interesting spontaneous resolution phenomenon.

Graphical abstract: LiCu2[BP2O8(OH)2]: a chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization

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Article information

DOI
https://doi.org/10.1039/C3DT50591J
Article type
Communication
Submitted
04 Mar 2013
Accepted
15 Mar 2013
First published
15 Mar 2013

Dalton Trans., 2013,42, 6298-6301

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LiCu2[BP2O8(OH)2]: a chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization

M. Yang, X. Li, J. Yu, J. Zhu, X. Liu, G. Chen and Y. Yan, Dalton Trans., 2013, 42, 6298 DOI: 10.1039/C3DT50591J

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