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Issue 24, 2013
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Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior

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Abstract

The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF4) and (T(p-OMe)PP)Ru(NO)(OC([double bond, length as m-dash]O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.

Graphical abstract: Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior

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Publication details

The article was received on 29 Dec 2012, accepted on 17 Feb 2013 and first published on 18 Feb 2013


Article type: Communication
DOI: 10.1039/C3DT33109A
Citation: Dalton Trans., 2013,42, 8537-8540
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    Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior

    D. Awasabisah, N. Xu, K. P. Sharmah Gautam, D. R. Powell, M. J. Shaw and G. B. Richter-Addo, Dalton Trans., 2013, 42, 8537
    DOI: 10.1039/C3DT33109A

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