Issue 24, 2013
From the journal:

Dalton Transactions

Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior†

Dennis Awasabisah,a   Nan Xu,a   Krishna P. Sharmah Gautam,b   Douglas R. Powell,a   Michael J. Shawb  and  George B. Richter-Addo*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Oklahoma, Stephenson Life Sciences Research Center, 101 Stephenson Parkway, Norman, OK 73019, USA
E-mail: grichteraddo@ou.edu
Fax: +1 (405) 325-6111
Tel: +1 405 325 4812

b Department of Chemistry, Box 1652, Edwardsville, IL 62026, USA

Abstract

The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF4) and (T(p-OMe)PP)Ru(NO)(OC([double bond, length as m-dash]O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.

Graphical abstract: Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior

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Article information

DOI
https://doi.org/10.1039/C3DT33109A
Article type
Communication
Submitted
29 Dec 2012
Accepted
17 Feb 2013
First published
18 Feb 2013

Dalton Trans., 2013,42, 8537-8540

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Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior

D. Awasabisah, N. Xu, K. P. Sharmah Gautam, D. R. Powell, M. J. Shaw and G. B. Richter-Addo, Dalton Trans., 2013, 42, 8537 DOI: 10.1039/C3DT33109A

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