Formation of a supramolecular assembly between a Na+-templated G-quartet and a Ni(II)–porphyrin complex

Yuji Inui; Shunichi Fukuzumi; Takahiko Kojima

doi:10.1039/C3DT33034F

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Formation of a supramolecular assembly between a Na⁺-templated G-quartet and a Ni(ii)–porphyrin complex†

Yuji Inui,^a Shunichi Fukuzumi*^ac and Takahiko Kojima*^b

Author affiliations

* Corresponding authors

^a Department of Material and Life Science, Graduate School of Engineering, Osaka University and ALCA (JST), 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp
Fax: (+) 81-6-6879-7370

^b Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan
E-mail: kojima@chem.tsukuba.ac.jp
Fax: (+) 81-29-853-4323

^c Department of Bioinspired Science, Ewha Womans University, Seoul 120-750, Korea

Abstract

Formation of a π–π stacked assembly between a Na⁺-templated G-quartet and octaethylporphyrinatonickel(II) was observed by spectroscopic methods in methanol/chloroform and the formation dynamics of the assembly was elucidated.

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Article information

DOI: https://doi.org/10.1039/C3DT33034F
Article type: Communication
Submitted: 18 Dec 2012
Accepted: 08 Jan 2013
First published: 14 Jan 2013

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Dalton Trans., 2013,42, 3779-3782

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Formation of a supramolecular assembly between a Na⁺-templated G-quartet and a Ni(II)–porphyrin complex

Y. Inui, S. Fukuzumi and T. Kojima, Dalton Trans., 2013, 42, 3779 DOI: 10.1039/C3DT33034F

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Dalton Transactions