Issue 18, 2013
From the journal:

Dalton Transactions

Smallest optical gap for quasi-one-dimensional iodo-bridged platinum compounds†

Minseob Shin,a   Shinya Takaishi,*a   Shohei Kumagai,a   Yutaro Ueda,a   Brian K. Breedlove,a   Hiroyuki Matsuzaki,b   Hiroshi Okamoto,b   Yusuke Wakabayashic  and  Masahiro Yamashita*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
E-mail: takaishi@mail.tains.tohoku.ac.jp, yamasita@agnus.chem.tohoku.ac.jp
Fax: +81-22-795-6547
Tel: +81-22-795-6545

b Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa 277-8561, Japan

c Division of Materials Physics, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

Abstract

We synthesized a series of one-dimensional (1D) iodo-bridged platinum compounds with long alkyl chains on the counterions. In the compounds, the shortest Pt⋯Pt distance and the smallest band gap thus far reported were achieved. These compounds were found to be in a CDW state by using synchrotron X-ray diffraction measurements.

Graphical abstract: Smallest optical gap for quasi-one-dimensional iodo-bridged platinum compounds

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Article information

DOI
https://doi.org/10.1039/C3DT32890B
Article type
Communication
Submitted
03 Dec 2012
Accepted
07 Jan 2013
First published
08 Jan 2013

Dalton Trans., 2013,42, 6277-6280

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Smallest optical gap for quasi-one-dimensional iodo-bridged platinum compounds

M. Shin, S. Takaishi, S. Kumagai, Y. Ueda, B. K. Breedlove, H. Matsuzaki, H. Okamoto, Y. Wakabayashi and M. Yamashita, Dalton Trans., 2013, 42, 6277 DOI: 10.1039/C3DT32890B

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