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Issue 7, 2013
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Small molecule activation by frustrated Lewis pairs

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Abstract

A series of frustrated Lewis pairs (FLPs) based on the Lewis acids tris(perchloroaryl)borane (BArCl), and tris(2,2′,2′′-perfluorobiphenyl)borane (PBB) and trialkylphosphines were prepared; their ability to effect the heterolytic cleavage of dihydrogen, insert carbon dioxide into the borohydride, and reduce the resulting formatoborate to methanol were studied. Additionally, the insertion of CO2 into a B–OH bond is explored with the ultimate aim of developing a homogeneous, catalytic preparation of carbonates. The compound [PBB–OH][H–P(tBu)3] was characterised by single crystal X-ray crystallography.

Graphical abstract: Small molecule activation by frustrated Lewis pairs

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Publication details

The article was received on 22 Oct 2012, accepted on 14 Nov 2012 and first published on 14 Nov 2012


Article type: Paper
DOI: 10.1039/C2DT32525J
Citation: Dalton Trans., 2013,42, 2431-2437
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    Small molecule activation by frustrated Lewis pairs

    A. L. Travis, S. C. Binding, H. Zaher, T. A. Q. Arnold, J. Buffet and D. O'Hare, Dalton Trans., 2013, 42, 2431
    DOI: 10.1039/C2DT32525J

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