Issue 1, 2013

Body-wing swapping in butterfly {FeIII2LnIII2} coordination clusters with triethylene glycol as ligand

Abstract

The first use of triethylene glycol (H2teg) in Fe/Ln chemistry affords two series of tetranuclear {FeIII2LnIII2} coordination clusters possessing defect-dicubane cores. A change in the synthetic procedure results in a different arrangement of the relative positions of the 3d and 4f elements offering a means to steer the structural and electronic features within a 3dā€“4f system.

Graphical abstract: Body-wing swapping in butterfly {FeIII2LnIII2} coordination clusters with triethylene glycol as ligand

Supplementary files

Article information

Article type
Communication
Submitted
25 Aug 2012
Accepted
04 Sep 2012
First published
04 Sep 2012

Dalton Trans., 2013,42, 46-49

Body-wing swapping in butterfly {FeIII2LnIII2} coordination clusters with triethylene glycol as ligand

G. Peng, G. E. Kostakis, Y. Lan and A. K. Powell, Dalton Trans., 2013, 42, 46 DOI: 10.1039/C2DT32027D

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