Issue 1, 2013
From the journal:

Dalton Transactions

A porous Sm(iii) coordination nanotube with hydrophobic and hydrophilic channels†

Nazario Lopez,a   Hanhua Zhao,a   Dan Zhao,b   Hong-Cai Zhou,a   Joseph P. Riebenspiesa  and  Kim R. Dunbar*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, USA
E-mail: dunbar@chem.tamu.edu

b Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore

Abstract

The π–π stacking interactions between tptz units from adjacent Sm(tptz)(HCOO)3 coordination nanotubes leads to additional 1D channels (tptz = 2,4,6-tris(2-pyridyl)-s-triazine). The present compound is a rare case of a tubular porous material with both hydrophobic and hydrophilic channels. Permanent porosity was confirmed by N2 adsorption isotherms.

Graphical abstract: A porous Sm(iii) coordination nanotube with hydrophobic and hydrophilic channels

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Article information

DOI
https://doi.org/10.1039/C2DT31842C
Article type
Communication
Submitted
12 Aug 2012
Accepted
12 Oct 2012
First published
02 Nov 2012

Dalton Trans., 2013,42, 54-57

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A porous Sm(III) coordination nanotube with hydrophobic and hydrophilic channels

N. Lopez, H. Zhao, D. Zhao, H. Zhou, J. P. Riebenspies and K. R. Dunbar, Dalton Trans., 2013, 42, 54 DOI: 10.1039/C2DT31842C

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