Issue 3, 2013
From the journal:

Dalton Transactions

Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†

Cristina Pubill-Ulldemolins,a   Macarena Poyatos,b   Carles Bo*a  and  Elena Fernández*c  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ). Avda. Països Catalans, 17. 43007 Tarragona, Spain

b Dpt. Química Inorgànica i Orgànica, Universitat Jaume I, Av Vicente Sos Baynat s/n, Castellón, Spain

c Dpt. Química Física i Iorgànica, Universitat Rovira i Virgili, C/Marcel.lí Domingo s/n, 43007 Tarragona, Spain
E-mail: mariaelena.fernandez@urv.cat
Web: http://www.quimica.urv.net/tecat/catalytic_organoborane_chemistry.php
Fax: (+) 34 977559563

Abstract

In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to favour a less energetically demanding route towards the formation of diborated products versus allyl boronate esters.

Graphical abstract: Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation

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Article information

DOI
https://doi.org/10.1039/C2DT31659E
Article type
Paper
Submitted
24 Jul 2012
Accepted
09 Oct 2012
First published
11 Oct 2012

Dalton Trans., 2013,42, 746-752

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Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation

C. Pubill-Ulldemolins, M. Poyatos, C. Bo and E. Fernández, Dalton Trans., 2013, 42, 746 DOI: 10.1039/C2DT31659E

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