Issue 47, 2013
From the journal:

CrystEngComm

Post-synthetic cation exchange in the robust metal–organic framework MIL-101(Cr)†

Petra Á. Szilágyi,*ab   Pablo Serra-Crespo,a   Iulian Dugulan,c   Jorge Gascon,a   Hans Geerlingsad  and  Bernard Dama  

* Corresponding authors

a Delft University of Technology, Department of Chemical Engineering, Julianalaan 136, Delft, The Netherlands

b Curtin University, Department of Imaging and Applied Physics, GPO Box U1987, Perth, WA 6845, Australia
E-mail: Petra.Szilagyi@curtin.edu.au

c Fundamental Aspects of Materials and Energy Group, Delft University of Technology, Mekelweg 15, 2629 JB Delft, The Netherlands

d Shell Technology Centre, Grasweg 31, Amsterdam, The Netherlands

Abstract

In this work an unambiguous proof of post-synthetic solvent-assisted cation exchange in the robust metal–organic framework MIL-101(Cr) is reported. Such substitution can alter directly the secondary building unit, which often defines the properties of the material.

Graphical abstract: Post-synthetic cation exchange in the robust metal–organic framework MIL-101(Cr)

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Article information

DOI
https://doi.org/10.1039/C3CE42006J
Article type
Communication
Submitted
04 Oct 2013
Accepted
09 Oct 2013
First published
09 Oct 2013

CrystEngComm, 2013,15, 10175-10178

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Post-synthetic cation exchange in the robust metal–organic framework MIL-101(Cr)

P. Á. Szilágyi, P. Serra-Crespo, I. Dugulan, J. Gascon, H. Geerlings and B. Dam, CrystEngComm, 2013, 15, 10175 DOI: 10.1039/C3CE42006J

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