Issue 31, 2013
From the journal:

CrystEngComm

Dihalogen-templated synthesis of dodecanuclear silver dichalcogenophosphate clusters†

Bing Li,a   Jian-Hong Liao,a   Yi-Juan Lia  and  C. W. Liu*a  

* Corresponding authors

a Department of Chemistry, National Dong Hwa University, Hualien 97401, Taiwan, R. O. C
E-mail: chenwei@mail.ndhu.edu.tw

Abstract

Dodecanuclear silver clusters, Ag12(μ5-X)2[E2P(OEt)2]10 (X = Br, I; E = S, Se), were isolated from the reaction of [Ag(CH3CN)4](PF6), dichalcogenophosphate ammonium salts and halides in a common organic solvent. The Ag12 ring consists of two identical Ag6 units linked by intermolecular Ag–E bonds. The geometry of a Ag6 motif can be described as a bicapped tetrahedron, which is stabilized by a rare pentacoordinated bromine/iodine atom as well as five 1,1-dichalcogenophosphate ligands.

Graphical abstract: Dihalogen-templated synthesis of dodecanuclear silver dichalcogenophosphate clusters

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Article information

DOI
https://doi.org/10.1039/C3CE40829A
Article type
Communication
Submitted
10 May 2013
Accepted
02 Jun 2013
First published
06 Jun 2013

CrystEngComm, 2013,15, 6140-6143

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Dihalogen-templated synthesis of dodecanuclear silver dichalcogenophosphate clusters

B. Li, J. Liao, Y. Li and C. W. Liu, CrystEngComm, 2013, 15, 6140 DOI: 10.1039/C3CE40829A

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