Issue 33, 2013
From the journal:

CrystEngComm

Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters†

Zhengguo Lin,‡a   Baokuan Chen,‡a   Xiao Feng,a   Bo Wang,*a   Yingnan Chi,a   Yanxuan Fan,a   Xinhang Yang,a   Xianqiang Huanga  and  Changwen Hu*a  

* Corresponding authors

a Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China
E-mail: bowang@bit.edu.cn, cwhu@bit.edu.cn
Fax: +86 10 68912631
Tel: +86 10 68912631

Abstract

Two new chiral hexanuclear palladium(II) complexes [Pd6(Cys)4(CysH)4][Pd6(CysH)8]Cl4·24H2O (1) and [Pd6(HCys)10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(II) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of L-Cys ligands can be preserved to the multinuclear Pd complexes.

Graphical abstract: Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

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Article information

DOI
https://doi.org/10.1039/C3CE40773J
Article type
Communication
Submitted
02 May 2013
Accepted
13 Jun 2013
First published
14 Jun 2013

CrystEngComm, 2013,15, 6461-6464

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Two chiral multinuclear palladium(II) complexes comprising alternately arranged isomerous hexanuclear clusters

Z. Lin, B. Chen, X. Feng, B. Wang, Y. Chi, Y. Fan, X. Yang, X. Huang and C. Hu, CrystEngComm, 2013, 15, 6461 DOI: 10.1039/C3CE40773J

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